Dielectric Studies of Hydroxyl-Carbonyl Complexes (Phenols with Acetophenone) |
Author(s): |
Anandhi R , Varuvan Vadivelan Institute of Technology, Dharmapuri, Tamilnadu , India; P. Krishnamurthi, Government Arts College, Dharmapuri, Tamilnadu , India |
Keywords: |
Hydrogen Bonding, Dipolar Increment, Hydroxyl-Carbonyl Complexes, Dipole Moment, Dielectric Constant |
Abstract |
The dipole moment of the 1:1 complexes of acetophenone and p-chloroacetophenone with phenol, o-chlorophenol, m-chlorophenol and p-chlorophenol at 303K have been determined by using Huysken's method based on the Onsager theory. The dipolar increments of the systems were computed from the experimental dipole moment of the complexes. The enhancement of the dipolar increment values confirms the hydrogen bonding between all the systems. The dipolar increment is negative indicate the predominant of polarization interaction taking place all the systems. |
Other Details |
Paper ID: IJSRDV4I110586 Published in: Volume : 4, Issue : 11 Publication Date: 01/02/2017 Page(s): 671-674 |
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